![]() ![]() IN NO EVENT SHALL CHANG BIOSCIENCE OR ITS SPONSORS BE LIABLE FOR ANY DIRECT, INDIRECT, INCIDENTAL, SPECIAL, EXEMPLARY, OR CONSEQUENTIAL DAMAGES (INCLUDING, BUT NOT LIMITED TO, PROCUREMENT OF SUBSTITUTE GOODS OR SERVICES LOSS OF USE, DATA, OR PROFITS OR BUSINESS INTERRUPTION) HOWEVER CAUSED AND ON ANY THEORY OF LIABILITY, WHETHER IN CONTRACT, STRICT LIABILITY, OR TORT (INCLUDING NEGLIGENCE OR OTHERWISE) ARISING IN ANY WAY OUT OF THE USE OF THIS SOFTWARE, EVEN IF ADVISED OF THE POSSIBILITY OF SUCH DAMAGE.Ĭopyright © 2002-2004 Chang Bioscience, Inc. Note the solid copper and silver were omitted from the expression. For the equilibrium between copper and silver ions: Cu (s) + 2Ag + Cu 2+ (aq) + 2Ag (s) The equilibrium constant expression is written as: Kc Cu 2+ / Ag + 2. THIS SOFTWARE IS PROVIDED BY CHANG BIOSCIENCE ``AS IS'' AND ANY EXPRESS OR IMPLIED WARRANTIES, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE ARE DISCLAIMED. Example Equilibrium Constant Calculation. Thanks for using our software! Please let us know your suggestions and comments. Ionization constant of a base, K d for the dissociation constant, etc.).įree energy changes in chemical reactions are linked to the equilibrium constant of the reaction by the equation Special cases of K eq (e.g., K a for the ionization constant of an acid, K b for the There are several common specific forms of equilibrium constant. K eq is a general term for equilibrium constant. Here, , and are concentrations of the chemical components. A special Cell Equilibrium calculation option is also available for. The Chemical Equilibrium Calculator helps researchers in chemical equilibrium constants related calculations. HSC chemistry, software for Process simulation, Reactions Equations and Equilibrium. Include all Primo 3.4, Abie 3.0, Heatmap Viewer, MicroHelper, Godlist Manager, label printing, and grade book. A great quick and practical reference for bench scientistsĪ collection of tools frequently used by bench biomedical scientists, ranging from centrifugationįorce conversion, molecular weight, OD, recipe calculators, to clinical calculators. Burton, in Modern Theoretical Chemistry, edited by B. The Electronic Protocol Book Table of contentsĪn electronic protocol book with 500 protocols andġ00 recipes. A computer simulation method for the calculation of equilibrium constants for the. to calculate the equilibrium constant for a simple bimolecular chemical reaction involving. ![]() Mac: Internet Explorer 5.0, IE5.1.4 or higher (IE5.1 will not work because of a bug.) PC: Internet Explorer 5.5 or higher and Netscape 4.08 or higher FastChem can be used in parallel or sequentially and is available under the GNU General Public License version 3 at together with several sample applications.Chemical Equilibrium Calculator Click here for more biology tools. The following calculator determines the ionic. The program is written in object-oriented C++ which makes it easy to couple the code with other programs, although a stand-alone version is provided. The ionic strength of a solution is a measure of the concentration of dissolved chemical constituents. ![]() Notably, the electron density is determined by using the method of Nelder and Mead at low temperatures. Specifically, the system of equations is decomposed into a set of coupled nonlinear equations in one variable each, which are solved analytically whenever feasible to reduce computation time. The applied method is based on the solution of a system of coupled non-linear (and linear) algebraic equations, namely the law of mass action and the element conservation equations including charge balance, in many variables. Solution: 1) The solution technique involves the use of what is. ![]() For the calculation of complex neutral/ionized gas-phase chemical equilibria, we present a semi-analytical, versatile, and efficient computer program, called FastChem. Calculate all three equilibrium concentrations when H2o I2o 0.200 M and Kc 64.0. ![]()
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![]() ![]() Straight in its pitch and unchanging melody His hand shoots for my throat faster than I can react His head hung slightly low in sudden contemplation and pain The adrenalin jack-knifing through my body like a restless rush of pure red almost bringing it to a halt I land an elbow directly to his face before I land fully catching him with my momentumĪll of my weight landing on his nose and mouth The lines across his wide brow/the shoulders of a man half-bull I have time to see his cold receding head, The time I hung there expanded for miles dying slower than normal I jumped into the air - I could see he hadn’t expected that No sympathy for an English ******* wanna be saviour like me. I call every mutilated thought I can from my mind and air Gently moving her body to one side I began to run at the man walking towards us The night mixing with the hopeless age of the station No more running.Īnd this is what I thought seconds before he was near us. Emotion.Īnd there was no-where else for us to go. His lips lay still like two grey worms on top of each other. I smile down telling her she can’t fool me with the same old tricks then I look too. Her laughter stopped like a match being put out. ![]() She was looking down to the end of the station where the entrance was. She began to curl into rest, her hair across my lap, but I notice that she sees one more thing before her eyes shut. I said one last thing to her to make her laugh a little, before we rested in wait for the last train. My back lay against the cold wood of the station seatĪnd the need for hope faded as we both began to sleep We kissed again, slowly and absolute - celebrating release The day stretched out and up into the evening as we laughed and screamed like two boiling oysters drunk in a kitchen time passed into and through the hours we wound around each other like two fighting seas her thighs tensing with absolute strength on my lap moaning from her stomach and into the sky There were no people or trains/we had five hours to burn until the next one came I pull her into myself.īut a shop was open in the blazing afternoonīut sold us enough with what we had to get us drunk We stand-up, and continue to walk through the breeze towards the train station. Her sighs and moans and thighs becoming louder. All of them.Īnd the heat kept beating, making me sweat.īut we always had enough energy to be together.Īs our bodies become hungrier, our need for each others skin increased. We had been travelling Europe for some time. Old beauty, future beauty.īulgaria, Estonia, Latvia. Muscles and waist growing tighter, thinner. The days and weeks we hadn’t been eating properly didn’t show on her figure as it did mine. I stepped out of many rooms only to find myself in the room I just left. I sang into the stoic mouths of storm drains. I grew my beard, an insomniac in a jail cell clinging to bars the color of a morning dove. I capitulated to the candor of a naked mattress. The moon over my shoulder tightened into focus like a prison spotlight. I dreamed of dead horseshoe ***** rolling in with the tide. Each morning I drew back the curtains and lost myself in the crisscrossing patterns of whitecaps, the synchronous flight of sanderlings above the dunes. I holed up for weeks in an oceanfront motel, dazed by the roar of the breakers. The sheriff extracted me from a ****** snowbank. I disappeared in a city lit by lavender streetlights, where buildings blotted out the stars and the traffic signals kept perfect time. I ran the tilt-a-whirl at the Ashtabula county fair, fattening up on fried Oreos and elephant ears, flirting behind tent ***** with the cute contortionist with strawberry-blonde hair. The typographically accurate Declaration of Independence inscribed on my back also confirms this. CCTV footage confirms I pawned a shotgun, a Gibson guitar, and my wife’s engagement ring at the pawnshop next to Fatty’s Tattoo parlor. How many miles does it take to turn yourself around, to rise up from ashes? Keep driving. Insects slapping the windshield like rain. Bluegreen glow of dashboard gauges, the faint scent of roadkill and desert marigolds. I stole my brother’s car and drove to Phoenix in the dark. She was without doubt unbearably titillating And except for a faint look of languor and ruin ![]() ![]() ![]() Get customer phone numbers, opening hours for every store in Tilton. Find the nearest location, opening hours and driving diections. Stores locations in Tilton, New Hampshire. Winnisquam Country Store and Deli, Tilton, New Hampshire. Winnisquam Country Store and Deli | Tilton NH. ET on Saturday in the second game of the 2023 USFL season. The Generals will square off against the Stallions at 7:30 p.m. Stallions final score, results: Alex McGough leads. Come find a great deal on used Jeeps in Manchester today! TrueCar has over 644,644 listings nationwide, updated daily. Used Jeeps for Sale in Manchester, NH (with Photos) - TrueCar. 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The Northeast region includes: Maine, Vermont, New Hampshire, Massachusetts, Rhode Island, Connecticut, New York, New Jersey, Pennsylvania, Delaware, District of … Northeast US 4×4 Off Road Clubs Directory - | No road, no problem. ![]() ![]() ![]() ![]() Perhaps ugh I hate even suggesting this, a nag bar could pop up when the user navigates back to the tab to inform them that the site was aggressively throttled.Īnyhow, I am glad you guys are getting out ahead of this, I think this stuff is going to get worse as sites seek to run more code on our machines in ways we cannot easily discern. And hopefully for legacy sites that won't be updated, the visual indicators above will clue users in as to fact that the browser is throttling the site. Perhaps a unthrottled-background permission request API can be done. I would figure that for larger more public facing devs, the experience might be a bit more tedious. They are mostly in house tools so as long as I can instruct users to override the throttle, provided I am given that option, which it seems like I will be. So I am fine with this being the default option even though it will break apps I have written. (A lot of this would be almost trivial by showing little cpu use bars, with a line where the throttle is, but it might look kind of ugly)Įven though this is going to break some of my apps, I can see a greater good here, and I am 100% for helping out with battery life, and preventing my machine from being some sort of ad network computation shard. ![]() * The ability via `site settings` to disable the throttling, however if a site is using excessive background resources, some sort of ui should show indicate such. Tab has throttling disabled by user-request. * A Visual Indicator on the tab, similar in spirit to the speaker or red recording circle, that conveysĢ. So to that end, communicating what's going on to the users, is I think pretty important so hopefully: However a lot of times they don't even know that it is and, surprise! the battery is drained, or everything is running slow and it's time to press shift+esc and stare at the jumping percentages in the task manager. If the user wants the site to run in the background, great. To me the fundamental issue is one of user control. To me `site settings` `Throttle this site when in the background, Warning: this may slow your machine and consume additional battery resources` (Maybe pinned will enlarge if document.title is changed or something don't know never use it). I use the text on there to communicate alerts / information to users. Pinning a tab has the side-effect of shrinking its title bar to just the icon. I'd love to reverse this and punish tabs that play audio in the background! (or to allow for genuinely useful uses, such as message alerts, punish those that play more then 5 seconds of audio in a minute, unless tey are whitelisted). > Tabs playing audio are already unthrottled How is "active" defined here? I foresee advertisers opening a websocket that does as little as possible in order to get a prompt-less lifting of the throttle. > disable aggressive throttling when active websocket connection is present. so if there is an opt out I expect it to be abused such that this pain point will not go away.Īs well as asking if a particular domain should be allowed to unthrottle itself as others have suggested (or instead of if there is a fear that extra UI interactions will confuse the user) perhaps you could only allow it if the top level frame also opts out? This would give control back to the main page maintainer and if used in combination with the prompts could confuse less technical users less (the request for unthrottling comes from a recognised name like not .com) and sometimes are two notable offenders here in my experience.Īdvertisers will opt of anything that might throttle their content whether they need to or not, without testing if they need to, just in case. ![]() The main problems I have with background tabs and resource use is advertising iframes on otherwise inert pages. > We will also consider more signals to use in exempting a page from this throttling I'd argue that Firefox's recent work in about:performance is actually more useful for this purpose (though isn't very good at dealing with large numbers of tabs that are each using only a small amount of CPU the real solution to that, though, should just be tab suspension). Realistically, you just can't use the Chrome task manager to find slow tabs :/. I know this, and have even complained about it in the past to Chrome engineers (as it allows an attacker way too much control over getting security sensitive tabs into the same process, further weakening the way overstated security benefits of having separate renderer processes, which is often muddled together with the actual/real benefit of separating processes by capability, as with rendering, networking, windowing, plugins, etc.), but there is also a limited number of processes: as I believe the default is 35, if you have more than 35 tabs open across all windows you are guaranteed to have some tabs sharing a process (by pidgeon hole principle). ![]() ![]() The solution employs a multi-layered security framework that combines a robust back-end infrastructure, end-to-end data security, network protections, access controls, and a full suite of security policies. 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Render all allies immune to poison, blind, silence, sleep, paralyze, dread, berserk, confuse, charm, doom, death, and stop for five turns.įor all allies and enemies with 1 BP or more, reduce BP by 1, and for those with -1 BP or less, raise BP by 1. Lower Physical Attack by 25%, but boost the effectiveness of recovery magic by 2.5 times.Īll elemental damage to all allies is halved for four turns. The selected ally absorbs all elemental damage for four turns.ĭamage to all allies and enemies will be nullified for two turns. Sacrifice 25% of your maximum MP to raise your BP by two. Invoke Shell on yourself for ten turns at the start of battle.īoost the target's elemental attacks to deal 1.5 times normal damage for five turns. ![]() Its Job Command is Spiritism.Īll elemental damage to the selected ally is nullified for four turns. The Spiritmaster's Specialty is Save WM MP. ![]() You can help the Bravely Default Wiki by expanding it. This article is too short to provide more than rudimentary information about the subject. ![]() ![]() ![]() Soon after, he was featured on the Bob Odenkirk album “Amateur Hour,” and later went on to tour with Odenkirk and select dates on the Bo Burnham Make Happy tour. In 2018, he released his debut LP, an ASMR album, entitled “An ASMR Album.” Wardell started doing standup in Washington DC in 2010, dropped out of Virginia Commonwealth University in 2013, and moved to Los Angeles in 2014. He’s been profiled in Rolling Stone, Vice, and other major publications. He starred in and wrote for the tragically underrated webseries “Like And Subscribe,” created by Wagner. Past guests include Vampire Weekend, Lizzo, and Tim Heidecker among others. He hosts a popular podcast with Jack Wagner called “Yeah, But Still,” which was placed on Vulture's list of The 10 Best Comedy Podcasts of 2020. Questions ? Visit our Frequently Asked Questions page!īrandon Wardell is a Filipino-American comedian, actor and podcaster known for his work on Comedy Central and for his appearances in Curb Your Enthusiasm (HBO), Like and Subscribe (Verizon), Special (Netflix) and I Think You Should Leave With Tim Robinson (Netflix). Tickets will be available for pick up at the box office prior to the show (they are generally available 1.5-2 hrs prior to showtime.) Please note, there is a 2 item per person minimum in the showroom. Management reserves the right to prevent customers from entering the facility who they deem disruptive or dangerous to other patrons. Don't miss this hilarious and heartwarming performance from one of the most promising comedians of our time. Filmed in Texas while on tour with Anjelah Johnson, this clean comedy special is appropriate for all audiences. This self-produced project delves into Mal's journey into fatherhood and is based on his experiences growing up in a single-parent household. Mal Hall's first comedy special, "The Ice Cream's Not Ready," was released in 2022 and is now available for streaming at or on YouTube by searching for MalHallTV. In addition to headlining his own comedy shows around the country, Mal can currently be found touring internationally as the main support act for comedians Anjelah Johnson and Alonzo Bodden. ![]() ![]() Performed on two nationwide college tours. He was a finalist for NBC's Standup for Diversity Competition and has also He has performed on stages across the country, including on hundreds of college campuses, and has made appearances on TV shows such as FOX's LAUGHS, AXS TV's MOCKPOCOLYPSE, and FuseTV's OFFBEAT. Mal is a nationally touring comedian who hails from San Diego. He has a conversational style, keen observations, and a cool delivery that has earned him a devoted following among young and old audiences alike. Mal Hall is a comedian, host, and online personality who has made a name for himself as one of the brightest up-and-coming comedians in the country. ![]() ![]() ![]() Using a sifter, dust the confectioner’s sugar over the top. Let cool completely on a cooling rack, 30 to 40 minutes. Spread the batter evenly into the prepared baking dish and top with the crumb topping, pressing lightly down into the cake.īake for 45 minutes, or until a toothpick inserted in the center comes out clean. Pour the wet mixture into the dry mixture and stir until smooth and thick. Step 2: Make the Cake Batter In a medium bowl, whisk together the flour, baking soda, baking powder, and salt. All crumb cakes are considered coffee cakes, but not all coffee cakes are crumb cakes. Coffee cake, on the other hand, is served with or without the crumb topping. Add the eggs, sour cream, and vanilla and mix until combined. Step 1: Make the Crumb Topping In a large bowl, combine the melted butter, granulated sugar, brown sugar, cinnamon, and. Crumb cake is any type of moist or dense cake that is typically topping with a streusel-type crumb topping. In a small bowl, mix together the butter and granulated sugar until smooth and creamy. In a large mixing bowl, whisk together the flour, baking soda, baking powder and salt. Generously grease a 9-inch springform pan and set aside. Do not overmix there should be large crumbles. For the crumb topping: ½ cup (62g) all-purpose flour ¼ cup (50g) granulated sugar ½ teaspoon cinnamon ¼ teaspoon nutmeg 3 Tablespoons (42g) unsalted butter cold and cubed Instructions Preheat your oven to 350 degrees F. Add the melted butter and flour and mix gently with a fork. In a medium bowl, mix together the brown sugar, granulated sugar, cinnamon and salt. In a medium bowl, whisk together the gluten free flour, granulated sugar, baking powder and salt. Step 2: Whisk Together The Dry Ingredients. ![]() If making homemade, make sure it is cool. All in all, it was a fabulous cake but next time, I will reduce the temp at 350 degrees which may keep to the origiinal baking time of almost one hour.Preheat the oven to 350☏. Follow the recipe for my homemade jam or you can use store bought. Even though the ends of the cake were slightly overdone, I just had the first piece and the cake itself was tender with a moist crumb. Next time, I may use parchment paper to line my pan. I also have a loaf pan coated in teflon but I did prepare the pan as you advised with butter and flour. Find Sweet Sams Baking Company Classic Crumb Cake, 18 oz at Whole Foods Market. I do realise that oven temps vary and admittedly, I was a little nervous about the 375 degree temp as stated in the recipe. At that time, I lowered the temp to 350 degrees and took the cake out of the oven afer exactly 49 minutes. I have a GE Proile electric oven and after 35 minutes in the oven, I felt the cake was starting to burn somewhat. Moist, vanilla flavored cake topped with crumbly cinnamon streusel and dusted with powdered sugar. First of all, I do whole heartedly agree that one needs to watch the timing of the baking. I just cut off an end piece of this cake and I will tell you my exprience while baking it. Chocolate chips – milk, dark, or semisweet, regular or mini chocolate chips.Greek yogurt – or you could use sour milk or buttermilk – room temperature.Whisk together the flour, baking powder, baking soda, and salt. Softened butter – I use salted although you can use unsalted butter just add a bit more salt Preheat the oven to 180C/350F/Gas 4, and grease a 13x9-inch pan.Crumb topping: This is a combination of flour, brown sugar, and room temperature butter.The original recipe uses a yeast dough, although a pastry crust could also be used. New York-Style Crumb Cake 5 cups all-purpose flour 2 cups firmly packed light brown sugar 1 tablespoon plus 1 teaspoons ground cinnamon 1 pound (4 sticks). It was about one inch thick, and had a very thick layer of crumbs. For room temperature ingredients remove from the fridge approximately 60 minutes before using, earlier if your house is cool.Ī crumb cake is a German cake known as a “Streuselkuchen”, it was a flat cake made on a baking sheet, then cut into oblong pieces. For the crumb topping: In a medium bowl, blend together the 2 1/2 cups of flour, light brown sugar, and cinnamon with a fork.*If you use unsalted butter then add ¼ teaspoon salt.How to freeze a Chocolate Chip Crumb Cake.What’s the difference between coffee cake and crumb cake?. ![]() |